Showing posts with label Ethanol. Show all posts
Showing posts with label Ethanol. Show all posts

How Biofuels Are Produced

From biomass to biofuels
From biomass to biofuels
Biomass resources run the gamut from corn kernels to corn stalks, from soybean and canola oils to animal fats, from prairie grasses to hardwoods, and even include algae.

In the long run, we will need diverse technologies to make use of these different energy sources. Some technologies are already developed; others will be. Today, the most common technologies involve biochemical, chemical, and thermochemical conversion processes.

Ethanol, today’s largest volume biofuel, is produced through a biochemical conversion process. In this process, yeasts ferment sugar from starch and sugar crops into ethanol. Most of today’s ethanol is produced from cornstarch or sugarcane. But biochemical conversion techniques can also make use of more abundant “cellulosic” biomass sources such as grasses, trees, and agricultural residues.

Researchers develop processes that use heat, pressure, chemicals, and enzymes to unlock the sugars in cellulosic biomass. The sugars are then fermented to ethanol, typically by using genetically engineered micro- organisms. Cellulosic ethanol is the leading candidate for replacing a large portion of U.S. petroleum use.

A much simpler chemical process is used to produce biodiesel. Today’s biodiesel facilities start with vegetable oils, seed oils, or animal fats and react them with methanol or ethanol in the presence of a catalyst. In addition, genetic engineering work has produced algae with a high lipid content that can be used as another source of biodiesel.

Algae are a form of biomass which could substantially increase our nation’s ability to produce domestic biofuels. Algae and plants can serve as a natural source of oil, which conventional petroleum refineries can convert into jet fuel or diesel fuel—a product known as “green diesel.”

Researchers also explore and develop thermochemical processes for converting biomass to liquid fuels. One such process is pyrolysis, which decomposes biomass by heating it in the absence of air. This produces an oil-like liquid that can be burned like fuel oil or re ned into chemicals and fuels, such as “green gasoline.” Thermochemical processes can also be used to pretreat biomass for conversion to biofuels.

Another thermochemical process is gasification. In this process, heat and a limited amount of oxygen are used to convert biomass into a hot synthesis gas. This “syngas” can be combusted and used to produce electricity in a gas turbine or converted to hydrocarbons, alcohols, ethers, or chemical products. In this process, biomass gasifiers can work side by side with fossil fuel gasifiers for greater flexibility and lower net greenhouse gas emissions.

In the future, biomass-derived components such as carbohydrates, lignins, and triglycerides might also be converted to hydrocarbon fuels. Such fuels can be used in heavy-duty vehicles, jet engines, and other applications that need fuels with higher energy densities than those of ethanol or biodiesel.

pH Measurements for Corn Mash Slurry (Liquefaction)

Yokogawa pH / ORP Sensors
Yokogawa pH / ORP Sensors

Application Description

Many Ethanol plants running today are using a combination style pH electrode with a non-flowing reference to measure pH in the Mash Slurry transfer line from the Mash slurry mix tank to cook. The Mash is being pumped out of the Mash Slurry tank is at approximately 82 °C and 2 to 4 bar (180 °F and 40 to 60 psig). The original pH electrode systems that were installed during plant construction are online retractable assemblies and are mounted in orientations from completely horizontal to completely vertical and everywhere in between.

The Problem

The combination probe that is being used will typically drift out of calibration very quickly. Also, the probe is damaged sometimes from excessive removal from the process. The reason this probe drifts out of calibration is due to the fact that the non-flowing reference system plugs and becomes fouled by the mash passing by it. pH measurements are only as good as the reference required to make this measurement. If the reference is not doing its job, the measurement electrode will drift.

Dry Mill Process


Product Recommendations

Yokogawa manufactures a multi-probe holder called the FF20 – flow through fitting or the FS20, which is pH chamber assembly with 1⁄2” NPT process connections. With these holders we use a combination electrode, part number: SC21C-AGC55 for measurement and reference and a separate temperature sensor part number: SM60-T1. The Yokogawa electrode system works due to the fact that the SC21C-AGC55 combination probe uses a pressurized reference system. By using plant air regulated to a KCl reservoir, the SC21C-AGC55 utilizes a positive flowing reference that does not foul.

Plants using this system typically check the pH measurement against a grab sample and only make adjustments if the sample and the online measured values are more than 0.2 pH difference from one another. Typically, the system will not need daily or weekly calibrations. Most plants will pull the electrodes once a month for cleaning and calibration in a standard 4 and 7 buffer solutions. 

pH probe locations
pH Probe Locations
Installation Considerations

The Yokogawa pH system is not retractable from the process. It is usually best to put the Yokogawa pH electrodes in a by-pass or recirculation line that you can add isolation valves for isolating the probes from the process for maintenance and calibration. The probe assembly should be mounted downstream of the Slurry Tank transfer pump. Ideally it will be in a recirculation line going back into the tank or into the suction side of the slurry pump.

The picture below shows an installation that is actually flowing from left to right. The arrows indicate the direction of the mash flow through the recirculation line and back into the suction side of the pump. You will get an idea of the installation of the Yokogawa probes and the pressurized reference KCl reservoir from this picture. The reservoir pressure is typically set 1 to 2 psig above the slurry line pressure. The KCl reservoir will require refilling every 2-3 months for most applications.

For more information contact:

Power Specialties, Inc.
9118 E. 72nd Terrace
Raytown, MO 64133
Toll Free: (800) 432-6550
Phone: (816) 353-6550
Fax: (816) 353-1740